Removal of Basic Dye Using Raw and Acid Activated Bentonite Samples

Abstract

The adsorption behavior of crystal violet (CV+) from aqueous solution onto raw (RB) and acid activated (AAB) bentonite samples was investigated as a function of parameters such as initial CV+ concentration, contact time and temperature. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms. The adsorption rate was fast and more than half of the adsorbed-CV+ was removed in the first 55 min for RB and 25 min for 0.2-AAB at the room temperature (C<inf>0</inf> = 1.2 mmol/g). The pseudo-first order, and pseudo-second order kinetic models were used to describe the kinetic data and rate constants were evaluated. The results best fit the pseudo-second order kinetic model with the rate constant, k<inf>2</inf>, in the range of 13.52 × 10-2 to 5.53 × 10-2 g/mmol and 52.70 × 10-2 to 6.69 × 10-2 mmol/g min for RB and 0.2-AAB sample, respectively (C<inf>0</inf> = 0.1-1.2 mmol/g). © 2008 Elsevier B.V. All rights reserved.