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A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-Like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3

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dc.authorscopusid16021063600
dc.authorscopusid37061591200
dc.authorscopusid55450090000
dc.authorscopusid16403949600
dc.authorscopusid35782527900
dc.authorscopusid37060821300
dc.authorscopusid37060821300
dc.contributor.authorÇolak, A.T.
dc.contributor.authorPamuk, G.
dc.contributor.authorUzun, N.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorSemerci, F.
dc.contributor.authorGünay, H.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T14:06:39Z
dc.date.available2020-06-21T14:06:39Z
dc.date.issued2013
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Çolak] Alper Tolga, Department of Chemistry, Dumlupinar Üniversitesi, Kutahya, Turkey; [Pamuk] Gönül, Department of Chemistry, Dumlupinar Üniversitesi, Kutahya, Turkey; [Uzun] Nazli, Department of Chemistry, Dumlupinar Üniversitesi, Kutahya, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Semerci] Fatih, Department of Chemistry, Kirklareli Üniversitesi, Kirklareli, Turkey; [Günay] Handan, Department of Chemistry, Dumlupinar Üniversitesi, Kutahya, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkeyen_US
dc.description.abstractIn this study, a novel organic-inorganic hybrid compound with AgNO<inf>3</inf> and 2,3-pyridinedicarboxylic acid (H<inf>2</inf>pydc), [Ag<inf>2</inf>(μ<inf>6</inf>-pydc)]<inf>n</inf>(1) has been synthesized. The molecular structure of complex has been determined by the single crystal X-ray diffraction. The complex has been observed to crystallize in the monoclinic space group P2<inf>1</inf>/c. The asymmetric unit of compound consists of two crystallographically different Ag(I) centers and one pydc ligand. The Ag1 and Ag2 adopt tetrahedral and T-shaped geometries, respectively. At the same time, the silver(I) compound consists of a fish bone similar to the 1D silver cluster. Furthermore, novel coordination mode shown by H<inf>2</inf>pydc indicates that the crystal exhibits photoluminescence in the solid state at room temperature. © 2012 Springer Science+Business Media New York.en_US
dc.identifier.doi10.1007/s10904-012-9798-1
dc.identifier.endpage423en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-84874726446
dc.identifier.scopusqualityQ1
dc.identifier.startpage418en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-012-9798-1
dc.identifier.volume23en_US
dc.identifier.wosWOS:000316061400019
dc.identifier.wosqualityQ1
dc.language.isoenen_US
dc.publisherSpringer Science and Business Media, LLCen_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.journalJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhotoluminescent Silver Complexen_US
dc.subjectPyridine-2,3-Dicarboxylate Complexen_US
dc.subjectSilver Clusteren_US
dc.subjectSilver(I) Complexen_US
dc.titleA Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-Like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3en_US
dc.typeArticleen_US
dspace.entity.typePublication

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