Publication: Synthesis of Novel Rhodium-Xylyl Linked N-Heterocyclic Carbene Complexes as Hydrosilylation Catalysts
| dc.authorscopusid | 7005334934 | |
| dc.authorscopusid | 7006702500 | |
| dc.authorscopusid | 8361848500 | |
| dc.authorscopusid | 36039473500 | |
| dc.authorscopusid | 7006471258 | |
| dc.contributor.author | Özdemïr, I. | |
| dc.contributor.author | Demi̇r, S. | |
| dc.contributor.author | Sahin, O. | |
| dc.contributor.author | Büyuk̈güngör, O. | |
| dc.contributor.author | Çetinkaya, B. | |
| dc.date.accessioned | 2020-06-21T15:17:58Z | |
| dc.date.available | 2020-06-21T15:17:58Z | |
| dc.date.issued | 2008 | |
| dc.department | Ondokuz Mayıs Üniversitesi | en_US |
| dc.department-temp | [Özdemïr] İsmail, Department of Chemistry, Inönü Üniversitesi, Malatya, Turkey; [Demi̇r] Serpil, Department of Chemistry, Inönü Üniversitesi, Malatya, Turkey; [Sahin] Onur, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis Üniversitesi, Samsun, Turkey; [Çetinkaya] Bekir, Department of Chemistry, Ege Üniversitesi, Izmir, Turkey | en_US |
| dc.description.abstract | Reaction of ortho-xylylbis(N-2,4,6-trimethylbenzylimidazolinium); xylylbis(N-butylimidazolinium) and para-xylylbis(N-2,4,6- trimethylbenzylimidazolinium); xylylbis(N-butylimidazolinium) salts with KOBut and [RhCl(COD)]<inf>2</inf> yields ortho- and paraxylylbis{(N-alkylimidazolidin-2-ylidene)chloro(η4-1, 5-cyclooctadiene) rho dium(I)) complexes (2a-d). All compounds synthesized were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of the 2a and 2d were determined by X-ray crystallography. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)-carbene complexes (2a-d), to give the corresponding silylethers in good yields (83-99%). Copyright © 2008 John Wiley & Sons, Ltd. | en_US |
| dc.identifier.doi | 10.1002/aoc.1353 | |
| dc.identifier.endpage | 66 | en_US |
| dc.identifier.issn | 0268-2605 | |
| dc.identifier.issn | 1099-0739 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.scopus | 2-s2.0-51449087989 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 59 | en_US |
| dc.identifier.uri | https://doi.org/10.1002/aoc.1353 | |
| dc.identifier.volume | 22 | en_US |
| dc.identifier.wos | WOS:000253691100013 | |
| dc.language.iso | en | en_US |
| dc.publisher | Wiley | en_US |
| dc.relation.ispartof | Applied Organometallic Chemistry | en_US |
| dc.relation.journal | Applied Organometallic Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Hydrosilylation | en_US |
| dc.subject | N-Heterocyclic Carbene | en_US |
| dc.subject | Rhodium | en_US |
| dc.subject | Xylylbis(Imidazolinium) Salts | en_US |
| dc.title | Synthesis of Novel Rhodium-Xylyl Linked N-Heterocyclic Carbene Complexes as Hydrosilylation Catalysts | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |