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One- and Two-Dimensional Heteropolynuclear Complexes with Tetracyanonickelate(II) and 2-Pyridinemethanol

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dc.authorscopusid37065112600
dc.authorscopusid49863490200
dc.authorscopusid16403949600
dc.authorscopusid7005267373
dc.authorscopusid36039473500
dc.contributor.authorSayin, E.
dc.contributor.authorKürkçüoǧlu, G.S.
dc.contributor.authorYeşilel, O.Z.
dc.contributor.authorT.
dc.contributor.authorBüyuk̈güngör, O.
dc.date.accessioned2020-06-21T13:56:52Z
dc.date.available2020-06-21T13:56:52Z
dc.date.issued2014
dc.departmentOndokuz Mayıs Üniversitesien_US
dc.department-temp[Sayin] Elvan, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Kürkçüoǧlu] Güneş Süheyla, Department of Physics, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [Yeşilel] Okan Zafer, Department of Chemistry, Eskişehir Osmangazi Üniversitesi, Eskisehir, Eskisehir, Turkey; [null] null, Department of Physics, Hacettepe Üniversitesi, Ankara, Turkey; [Büyuk̈güngör] Orhan, Department of Physics, Ondokuz Mayis University Faculty of Science and Arts, Samsun, Turkeyen_US
dc.description.abstractThree new cyano complexes, [Cu(hmp)<inf>2</inf>] [Cu(hmpH)<inf>2</inf>Ni(μ-CN)<inf>2</inf>(CN)<inf>2</inf>]<inf>2</inf>·4H<inf>2</inf>O (1), [Zn<inf>3</inf>(hmp)<inf>2</inf>(hmpH)<inf>4</inf>-Ni<inf>2</inf>(μ-CN)<inf>6</inf>(CN)<inf>2</inf>]·2H<inf>2</inf>O (2) and [Cd<inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>(hmpH)<inf>2</inf>Ni(μ-CN)<inf>4</inf>Ni(μ-CN)<inf>2</inf>(CN)<inf>2</inf>] (3) (2-pyridinemethanol abbreviated to hmpH), have been synthesized and characterized by elemental analysis, vibrational spectroscopy (FT-IR and Raman), thermal and single-crystal X-ray diffraction analyses. In 1, Cu(II) ions are connected by the tetracyanonickelate(II) anions to form one-dimensional (1D) zig-zag chains. In 2, tetracyanonickelate(II) ions are coordinated to the neighboring three Zn(II) ions to form a one-dimensional double chain structure. In 3, Cd(II) ions are connected by tetrakis-monodentate tetracyanonickelate(II) ions to form a one-dimensional ladder-like chain. Adjacent ladder-like chains are linked by the bis-monodentate tetracyanonickelate(II) ions to generate a 2D network. The 3D supramolecular network of the complexes constructed by intermolecular interactions such as Ni···π, C-H···Ni, π···π and hydrogen bonding interactions.en_US
dc.identifier.doi10.1515/zkri-2014-1756
dc.identifier.endpage572en_US
dc.identifier.issn2194-4946
dc.identifier.issn2196-7105
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-84990997241
dc.identifier.scopusqualityQ4
dc.identifier.startpage563en_US
dc.identifier.urihttps://doi.org/10.1515/zkri-2014-1756
dc.identifier.volume229en_US
dc.identifier.wosWOS:000343696900004
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherWalter de Gruyter GmbH peter.golla@degruyter.comen_US
dc.relation.ispartofZeitschrift Fur Kristallographie-Crystalline Materialsen_US
dc.relation.journalZeitschrift Fur Kristallographie-Crystalline Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2-Pyridinemethanol Complexesen_US
dc.subjectC-H··Ni Interactionen_US
dc.subjectCyanide Complexesen_US
dc.subjectNi···Π Interactionen_US
dc.subjectO-H···O Interactionen_US
dc.subjectTetracyanonickelate(II) Complexesen_US
dc.subjectΠ···Π Interactionen_US
dc.titleOne- and Two-Dimensional Heteropolynuclear Complexes with Tetracyanonickelate(II) and 2-Pyridinemethanolen_US
dc.typeArticleen_US
dspace.entity.typePublication

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